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Zinc Cyanide Silver Gold Precipitation

This dissociation is said to be increased in the presence of free alkali. The addition of mineral acid to solutions of sodium zinc cyanide first precipitates zinc cyanide NaL2Zn(CN)4 + 2 HCl = Zn(CN)2 + 2 HCN + 2 NaCl. and then, as more acid is added, the zinc cyanide is decomposed to hydrocyanic acid.

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